5114-84-1

Basic information

• Product Name: (1,3-dimethyl-1,3-dihydro-2H-benzoimidazol-2-ylidene)acetonitrile
• Synonyms: (1,3-dimethyl-1,3-dihydro-2H-benzoimidazol-2-ylidene)acetonitrile
• CAS NO: 5114-84-1
• Molecular Weight: 185.228
• Mol File: 5114-84-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1,3-dimethyl-1,3-dihydro-2H-benzoimidazol-2-ylidene)acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (1,3-dimethyl-1,3-dihydro-2H-benzoimidazol-2-ylidene)acetonitrile(5114-84-1)
• EPA Substance Registry System: (1,3-dimethyl-1,3-dihydro-2H-benzoimidazol-2-ylidene)acetonitrile(5114-84-1)

Safety Data

• Hazardous Substances Data: 5114-84-1(Hazardous Substances Data)

Upstream product

• 2735-62-8 (1-methylbenzimidazol-2-yl)acetonitrile 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 1228793-52-9 2-(2-amino-5-(4-ethylphenyl)-3-furanyl)-1,3-dimethyl-1H-benzimidazolium bromide 
• 1228793-51-8 2-(2-amino-5-phenyl-3-furanyl)-1,3-dimethyl-1H-benzimidazolium bromide 
• 1228793-53-0 2-(2-amino-5-(4-bromophenyl)-3-furanyl)-1,3-dimethyl-1H-benzimidazolium bromide 
• 948301-87-9 5-amino-4-(2,3-dihydro-1,3-dimethylbenzimidazol-2-yl)-2,3-dihydro-1-(4-methoxyphenyl)pyrrol-3-one 
• 948301-86-8 5-amino-4-(2,3-dihydro-1,3-dimethylbenzimidazol-2-yl)-1-(4-ethylphenyl)-2,3-dihydropyrrol-3-one 
• 948301-72-2 5-amino-4-(2,3-dihydro-1,3-dimethylbenzimidazol-2-yl)-2,3-dihydro-1-phenylpyrrol-3-one 

Relevant articles and documents

Synthesis and properties of 3-cyano-3-hetaryl-ylidene-2-oxopropyl ethanethioates and 4-cyano-4-hetarylylidene-3-oxobutyl ethanethioates

Acylation of hetarylacetonitriles and hetarylylideneacetonitriles with acetylmercaptoacetyl chloride gave 3-cyano-3-hetarylylidene-2-oxopropyl ethanethioates. 2-Amino-3-hetaryl-4(5H)oxothio-phenes or 2-hetarylylidene-3-oxo- 4-sulfanylbutanenitriles were obtained on treating them with bases. Acylation of hetarylacetonitriles with 3-acetylmercaptopropionyl chloride gave 4-cyano-4-hetaryl-ylidene-3-oxobutyl ethanethioates, deacetylation of which gave 2-hetarylylidene-3-oxo-5-sulfanyl-pentanenitriles.