511546-04-6

Basic information

• Product Name: (9S)-austrodoral
• CAS NO: 511546-04-6
• Molecular Weight: 208.344
• Mol File: 511546-04-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (9S)-austrodoral(CAS DataBase Reference)
• NIST Chemistry Reference: (9S)-austrodoral(511546-04-6)
• EPA Substance Registry System: (9S)-austrodoral(511546-04-6)

Safety Data

• Hazardous Substances Data: 511546-04-6(Hazardous Substances Data)

Upstream product

• 79886-54-7 11-nordrimane-8α,9β-diol 

Relevant articles and documents

Regioselective 1,2-Diol Rearrangement by Controlling the Loading of BF3·Et2O and Its Application to the Synthesis of Related Nor-Sesquiterene- and Sesquiterene-Type Marine Natural Products

The regiocontrolled rearrangement of 1,2-diols has been achieved by controlling the loading of BF3·Et2O. Its applicability is showcased by the divergent synthesis of austrodoral, austrodoric acid, and 8-epi-11-nordriman-9-one, as well as a formal synthesis of siphonodictyal B and liphagal. A new light is shed on piancol-type rearrangements that will be useful in diversity-oriented synthesis of related natural products.