51203-49-7

Basic information

• Product Name: Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99%
• Synonyms: Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99%;Cyclopentadienyl(cycloheptatrienyl)titaniuM(II),99%;(eta7-Cycloheptatrienyl)(eta5-cyclopentadienyl)titanium(II);5-cyclopentadienyl)titanium(II);7-Cycloheptatrienyl)(η(η7-Cycloheptatrienyl)(η5-cyclopentadienyl)titanium(II);(eta7-Cycloheptatrienyl)(eta5-cyclopentadienyl)titanium(II) (&eta
• CAS NO: 51203-49-7
• Molecular Formula: C₁₂H₁₂Ti
• Molecular Weight: 204.09068
• Product Categories: metallocene
• Mol File: 51203-49-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 118.5°Cat760mmHg
• Flash Point: 6.1°C
• Appearance: blue/crystal
• Density: g/cm³
• Vapor Pressure: 19.9mmHg at 25°C
• Sensitive: air sensitive
• CAS DataBase Reference: Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99%(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99%(51203-49-7)
• EPA Substance Registry System: Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99%(51203-49-7)

Safety Data

• RIDADR: 1325
• HazardClass: 4.1
• PackingGroup: II
• Hazardous Substances Data: 51203-49-7(Hazardous Substances Data)

Usage

General Description

Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99% is a chemical compound that consists of a titanium atom bonded to both a cyclopentadienyl and a cycloheptatrienyl ligand. It is a highly pure compound, with a 99% purity level. This chemical is often used as a catalyst in various organic chemical reactions, such as polymerization and olefin metathesis. It is known for its stability and effectiveness in facilitating these types of reactions, and its high purity level ensures consistent and reliable results. Overall, Cyclopentadienyl(cycloheptatrienyl)titanium(II), 99% is a valuable and versatile chemical compound with various industrial applications.

InChI:InChI=1/C7H7.C5H5.Ti/c1-2-4-6-7-5-3-1;1-2-4-5-3-1;/h1-7H;1-5H;/q-7;-1;

Upstream product

• 1271-19-8 bis(cyclopentadienyl)titanium dichloride 
• 544-25-2 Cyclohepta-1,3,5-triene 
• 1270-98-0 cyclopentadienyl titanium(IV) trichloride 
• 7439-95-4 magnesium 

Downstream Products

• 82666-30-6 [titanium(II)(η5-cyclopentadienyl)(η7-C7H6PPh2)] 

Relevant articles and documents

Exploring the Organometallic Route to Molecular Spin Qubits: The [CpTi(cot)] Case

The coherence time of the 17-electron, mixed sandwich complex [CpTi(cot)], (η8-cyclooctatetraene)(η5-cyclopentadienyl)titanium, reaches 34 μs at 4.5 K in a frozen deuterated toluene solution. This is a remarkable coherence time for a highly protonated molecule. The intramolecular distances between the Ti and H atoms provide a good compromise between instantaneous and spin diffusion sources of decoherence. Ab initio calculations at the molecular and crystal packing levels reveal that the characteristic low-energy ring rotations of the sandwich framework do not yield a too detrimental spin-lattice relaxation because of their small spin–phonon coupling. The volatility of [CpTi(cot)] and the accessibility of the semi-occupied, non-bonding d (Formula presented.) orbital make this neutral compound an ideal candidate for single-qubit addressing on surface and quantum sensing in combination with scanning probe microscopy.