51248-27-2Relevant academic research and scientific papers
Diradical reaction mechanisms in [3 + 2]-cycloadditions of hetaryl thioketones with alkyl- or trimethylsilyl-substituted diazomethanes
Mlostoń, Grzegorz,Pipiak, Paulina,Heimgartner, Heinz
, p. 715 - 724 (2016)
Reactions of dihetaryl and aryl/hetaryl thioketones with 2-diazopropane, diazoethane, and (trimethylsilyl)diazomethane were studied at variable temperature. The experiments showed that reactions with 2-diazopropane carried out at -75°C occur mainly via th
