512803-12-2Relevant academic research and scientific papers
Synthesis, crystal structure and DFT calculations on 2,6-diisopropylphenylcopper; its use in the preparation of dichloro-2,6-diisopropylphenylphosphine
Boeré, René T.,Masuda, Jason D.,Tran, Peter
, p. 5597 - 5603 (2006)
The homoleptic aryl copper reagent [Cu4Dipp4] (Dipp = 2,6-diisopropylphenyl) has been prepared and structurally characterized by a single-crystal X-ray diffraction study. Its tetrameric structure differs in significant details from t
2,6-Diisopropylphenylphosphane: A new, bulky primary phosphane and its mono- and disilylated Si(CH3)3 and Si(CH3)2-t-Bu derivatives - A synthetic, crystallographic, and dynamic NMR investigation
Boere, Rene T.,Masuda, Jason D.
, p. 1607 - 1617 (2002)
The bulky primary phosphane 2,6-diisopropylphenylphosphane, DipPH2, has been prepared from 1-bromo-2,6-diisopropylbenzene via the reaction of the Grignard reagent with PCl3. The resulting mixed phosphonous dihalides DipP(Cl,Br)2
Phosphine-catalysed reductive coupling of dihalophosphanes
Hering-Junghans, Christian,Schumann, André,Siewert, Jan-Erik
supporting information, p. 15111 - 15117 (2021/11/12)
Classically tetraaryl diphosphanes have been synthesized through Wurtz-type reductive coupling of halophosphanes R2PX or more recently, through the dehydrocoupling of phosphines R2PH. Catalytic variants of the dehydrocoupling reactio
