51287-99-1Relevant academic research and scientific papers
Telechelic oligomers by halogen atom transfer radical addition
Bellesia, Franco,Forti, Luca,Gallini, Elena,Ghelfi, Franco,Libertini, Emanuela,Pagnoni, Ugo M.
, p. 7849 - 7856 (1998)
Monodispersed telechelic oligomers have been efficiently prepared by Fe0-FeCl3 promoted halogen atom transfer radical of functional telogens and taxogens.
Addition of α-polyhalides to olefins under mild reaction conditions, catalyzed by Mo(CO)6
Shvo, Youval,Green, Revital
, p. 77 - 83 (2007/10/03)
Mo(CO)6 was found to be an efficient pre-catalyst in the 1,2-addition reaction of α-polyhalides to various olefins. Significantly, the reaction was run under mild conditions, viz. refluxing acetonitrile, with satisfactory yields. Cr(CO)6/
The Fe0 promoted addition of CCl4 and CCl3Br to olefins
Bellesia, Franco,Forti, Luca,Ghelfi, Franco,Pagnoni, Ugo M.
, p. 961 - 971 (2007/10/03)
The radical addition of CCl4 or CCl3Br to olefins is efficiently promoted by iron filings in N,N-dimethylformamide under mild conditions.
ADDITION OF TETRACHLOROMETHANE TO 1,5-HEXADIENE
Kotora, Martin,Hajek, Milan
, p. 393 - 396 (2007/10/02)
The 2:1 adduct as the final product of the addition of tetrachloromethane to 1,5-hexadiene catalyzed by copper(I)-butylamine complex was obtained in high yield (96percent) under mild reaction conditions.Predominant 1:1 adduct formation was observed in the presence of a palladium catalyst or dibenzoyl peroxide initiator.
METAL-OXIDE INDUCED REDOX CHAIN ADDITION OF TETRACHLOROMETHANE TO A CARBON-CARBON DOUBLE BOND
Hajek, Milan,Silhavy, Premysl,Malek, Jaroslav
, p. 3488 - 3501 (2007/10/02)
Formation of 1:1 adducts in the addition of tetrachloromethane to a terminal carbon-carbon double bond was investigated at 76-200 deg C.The redox chain addition reaction with 1-octene, electron-deficient alkenes and unconjugated aliphatic dienes induced by catalytic amounts of copper(I) or copper(II) oxides in conjugation with diethylamine or diisopropylamine afforded the corresponding 1:1 adducts up to in 85percent yields.Aliphatic 1,3-dienes underwent redox chain 1,4-addition giving isomeric 1,1,1,5-tetrachloro-3-alkenes.
Iron Carbonyl Promoted Additions of Perhalomethanes to Carbon-Carbon Double Bonds
Elzinga, J.,Hogeveen, H.
, p. 3957 - 3969 (2007/10/02)
The addition of CCl4 and CBrCl3 to carbon-carbon double bonds, catalyzed by Fe2(CO)9 and Me3NFe(CO)4, is reported.In the case of CCl4, these reactions afford α,α,α,γ-tetrachloro-substituted derivatives with simple alkenes, whereas with norbornadiene and w
