513-37-1 Usage
Chemical Properties
Liquid.
Uses
Different sources of media describe the Uses of 513-37-1 differently. You can refer to the following data:
1. Dimethylvinyl chloride is not used commercially, but is used for research purposes. It has been used in organic syntheses and as a chemical intermediate for the production of isobutylene compounds for laboratory use (IARC 1995, HSDB 2009).
2. 1-Chloro-2-methylpropene was used to study multiple infrared photon excitation of α-chloro olefins.
General Description
Clear dark yellow to pale orange liquid.
Air & Water Reactions
Highly flammable. May be sensitive to prolonged exposure to air and light. Slightly soluble in water.
Reactivity Profile
1-CHLORO-2-METHYL-1-PROPENE is incompatible with strong oxidizing agents and strong bases.
Hazard
Carcinogen; neoplastigen; moderately toxic; local irritant, and narcotic.
Fire Hazard
1-CHLORO-2-METHYL-1-PROPENE is flammable.
Carcinogenicity
Dimethylvinyl chloride is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
Check Digit Verification of cas no
The CAS Registry Mumber 513-37-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,1 and 3 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 513-37:
(5*5)+(4*1)+(3*3)+(2*3)+(1*7)=51
51 % 10 = 1
So 513-37-1 is a valid CAS Registry Number.
InChI:InChI=1/C4H7Cl/c1-4(2)3-5/h3H,1-2H3
513-37-1Relevant articles and documents
Landgrebe,J.A.,Mathis,R.D.
, p. 3545 - 3552 (1966)
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine: Carbene, diazo and rearrangement in excited state
Wakahara, Takatsugu,Niino, Yasuyuki,Kato, Takashi,Maeda, Yutaka,Akasaka, Takeshi,Liu, Michael T. H.,Kobayashi,Nagase
, p. 9465 - 9468 (2007/10/03)
C60 acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the photolysis of 3-chloro-3-isopropyldiazirine and 3-chloro-3-chloromethyldiazirine. The carbene adds to C60 to form methanofullerene, whereas the diazo compound adds to C60 to form fulleroid. The olefin product arises as a result of the rearrangement in the excited state.
Quaternary ammonium polychlorides as efficient reagents for chlorination of unsaturated compounds
Zelikman,Tyurin,Smirnov,Zyk
, p. 1541 - 1546 (2007/10/03)
Chlorination of unsaturated compounds by benzyltributylammonium polychlorides results in higher yields of addition products compared to those obtained with molecular chlorine.
