51318-08-2

Basic information

• Product Name: ((Z)-3,3-Dimethyl-2-phenyl-but-1-enyl)-trimethyl-silane
• CAS NO: 51318-08-2
• Molecular Weight: 232.441
• Mol File: 51318-08-2.mol

Chemical Properties

• CAS DataBase Reference: ((Z)-3,3-Dimethyl-2-phenyl-but-1-enyl)-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((Z)-3,3-Dimethyl-2-phenyl-but-1-enyl)-trimethyl-silane(51318-08-2)
• EPA Substance Registry System: ((Z)-3,3-Dimethyl-2-phenyl-but-1-enyl)-trimethyl-silane(51318-08-2)

Safety Data

• Hazardous Substances Data: 51318-08-2(Hazardous Substances Data)

Upstream product

• 118297-83-9 (Z)-1-tert-butyl-2-(trimethulsilyl)vinyl diphenyl phosphate 
• 938-16-9 2,2-dimethylpropiophenone 
• 1066-64-4 tetrakis(trimethylsilyl)methane 
• 1068-69-5 Tris(trimethylsilyl)methane 

Relevant articles and documents

Synthesis of Vinyl Silanes from Vinyl Silane Phosphates

To develop a new synthesis of vinyl silanes, a representative set of vinyl silane phosphates (VSP's) has been treated with several organocuprate reagents.With acyclic VSP's, phosphate substitution proceeds in generally good yields, giving a single stereoisomer of the vinyl silane with retention of the VSP stereochemistry.In the cyclic systems examined, yields are generally somewhat lower under the same reactions conditions.However, this new sequence offers a regiochemistry complementary to other syntheses of cyclic vinyl silanes, and an approach to higly substituted vinyl silanes applicable to both cyclic and acyclic systems.