51319-09-6

Basic information

• Product Name: 2,5-Cyclohexadien-1-one, 4-ethyl-4-methyl-
• CAS NO: 51319-09-6
• Molecular Formula: C9H12O
• Molecular Weight: 136.194
• Mol File: 51319-09-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadien-1-one, 4-ethyl-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadien-1-one, 4-ethyl-4-methyl-(51319-09-6)
• EPA Substance Registry System: 2,5-Cyclohexadien-1-one, 4-ethyl-4-methyl-(51319-09-6)

Safety Data

• Hazardous Substances Data: 51319-09-6(Hazardous Substances Data)

Upstream product

• 17429-32-2 4-ethyl-4-methyl-2-cyclohexene-1-one 
• 35155-49-8 4-ethyl-4-methylcyclohexan-1-one 
• 108-75-8 2,4,6-trimethyl-pyridine 
• 108153-30-6 4-ethyl-2,6-dibromo-4-methyl-cyclohexanone 

Downstream Products

• 1123-94-0 4-ethyl-m-cresol 
• 49576-83-2 Bis-2-(4-methyl-4-ethylcyclohexa-2,5-dienyl)-diselenid 
• 6161-67-7 3-ethyl-4-methyl-phenol 

Relevant articles and documents

Strong and Confined Acids Control Five Stereogenic Centers in Catalytic Asymmetric Diels–Alder Reactions of Cyclohexadienones with Cyclopentadiene

We describe a highly enantioselective Diels–Alder reaction of cross-conjugated cyclohexadienones with cyclopentadiene, in which five stereocenters are effectively controlled by a strongly acidic and confined imidodiphosphorimidate catalyst. Our approach provides tricyclic products in excellent stereoselectivity. We also report methods to convert the obtained products into useful intermediates and a computational study that aids in gaining deeper insight into the reaction mechanism and origin of stereoselectivity.