51349-92-9Relevant academic research and scientific papers
Efficient Conversion of Olefins into Epoxides, Bromohydrins, and Dibromides with Sodium Bromide in Water-Organic Solvent Electrolysis Systems
Torii, Sigeru,Uneyama, Kenji,Tanaka, Hideo,Yamanaka, Tooru,Yasuda, Tsuneo,et al.
, p. 3312 - 3315 (2007/10/02)
Selective functionalizations of dimethyl 4-cyclohexene-1,2-dicarboxylate (1) and acyclic olefins 5 into the corresponding epoxides 2 and 6, bromohydrins 3 and 7, and 1,2-dibromides 4 and 8 were performed by electrolysis in a MeCN-H2O-NaBr-(Pt) system.Lowe
KINETICS OF THE EPOXIDATION OF CYCLOALKENES BY AQUEOUS SOLUTIONS OF PERACETIC ACID
Batog, A. E.,Savenko, T. V.,Batrak, T. A.,Kucher, R. V.
, p. 1860 - 1862 (2007/10/02)
The kinetics of the oxidation of a series of cycloalkenes with various structures at 10-40 deg C by peracetic acid were studied.The kinetic and activation parameters of the reaction were obtained, and the validity of the isokinetic relationship for the given reaction series was demonstrated.The calculated isokinetic temperature, equal to 3 deg C, lies in a range of temperatures close to the investigated range, and this is reflected in the slight dependence of the reaction rate on the structure of the cycloalkenes.
KINETICS OF THE REACTION OF ALICYCLIC MONOEPOXIDES WITH CARBOXYLIC ACIDS
Batog, A. E.,Stepko, O. P.,Nikonova, L. P.
, p. 971 - 975 (2007/10/02)
Alicyclic monoepoxides and monocyclohexyl esters of 4-cyclohexene-1,2-dicarboxylic and 5-norbornene-2,3-dicarboxylic acids were synthesized.The kinetics of the nonkatalytic reaction of the monoepoxides with carboxylic acids in the mass at 100-160 deg C we
