51367-95-4Relevant academic research and scientific papers
Cationic polycyclizations of polyenes via their bromohydrins. II. Synthesis of (±)-aplysistatin
Gosselin,Rouessac
, p. 5515 - 5518 (1983)
A synthesis of (±) aplysistatin 1 from geraniol is described in which the key step is the electrophilic cyclization of the bromohydrin 8.
Process for the preparation of terpenes
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, (2008/06/13)
A terpene compound having the formula (III) is produced by reacting an allylic halide having the formula (I) with a Grignard reagent having the formula (II) in the presence of anhydrous zinc chloride and a copper compound or an organic zinc halide compound having the formula (IV) in the presence of a copper compound, provided that when A-A is C-C, R' is hydrogen and when A-A is C=C, X is chlorine. STR1
