51385-54-7

Usage

InChI:InChI=1/C7H13FO5/c1-12-7-6(11)5(10)4(8)3(2-9)13-7/h3-7,9-11H,2H2,1H3/t3-,4+,5+,6-,7-/m1/s1

Upstream product

• 31873-35-5 methyl 6-O-benzoyl-2,3-di-O-benzyl-β-D-glucopyranoside 
• 74801-22-2 methyl 2,3-di-O-benzyl-6-O-(tert-butyldimethylsilyl)-4-O-(methylsulfonyl)-β-D-glucopyranoside 
• 20688-89-5 Methanesulfonic acid (2R,3R,4R,5R,6R)-4,5-bis-benzyloxy-2-hydroxymethyl-6-methoxy-tetrahydro-pyran-3-yl ester 
• 6988-40-5 methyl 2,3-di-O-benzyl-β-D-glucopyranoside 
• 79698-14-9 methyl 6-O-benzoyl-2,3-di-O-benzyl-4-O-(methylsulfonyl)-β-D-glucopyranoside 
• 79698-15-0 methyl 6-O-benzoyl-2,3-di-O-benzyl-4-deoxy-4-fluoro-β-D-glucopyranoside 
• 13035-24-0 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 51996-35-1 methyl 2,3-di-O-benzyl-4-deoxy-4-fluoro-β-D-galactopyranoside 

Relevant academic research and scientific papers

Preparation of two methyl deoxyfluoro-beta-D-galactopyranosides, and their interaction with galactan-specific immunoglobulin A J539 (Fab').

Methyl 2-deoxy-2-fluoro-beta-D-glactopyranoside (2) and methyl 4-deoxy-4-fluoro-beta-D-glactopyranoside (7) have been prepared, and the possibility of their binding to (1 leads to 6)-beta-D-galactopyranan-specific immunoglobulin A J539 (Fab') has been investigated. Compound 2 does not show binding, whereas 7 does. It appears that the 2-hydroxyl group of methyl beta-D-galactopyranoside may take part in hydrogen bonding to the protein.

Specificity of α- and β-D-galactosidase towards analogs of D-galactopyranosides modified at C-4 or C-5

In examining the stereochemistry of D-galactose oxidase, it was found that some 4-deoxy analogs of methyl β-D-galactopyranoside (1), particularly the 4-amino (2) and 4-fluoro (3) derivatives, are relatively good substrates of the enzyme.The same compounds