51391-19-6

Basic information

• Product Name: METHYL METH-D3-ACRYLATE
• Synonyms: METHYL METH-D3-ACRYLATE
• CAS NO: 51391-19-6
• Molecular Formula: C5H5D3O2
• Molecular Weight: 103.13
• Mol File: 51391-19-6.mol
• Article Data: 3

Chemical Properties

• Melting Point: -48 °C(lit.)
• Boiling Point: 100 °C(lit.)
• Flash Point: 10 °C
• Appearance: /
• Density: 0.964 g/mL at 25 °C
• CAS DataBase Reference: METHYL METH-D3-ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL METH-D3-ACRYLATE(51391-19-6)
• EPA Substance Registry System: METHYL METH-D3-ACRYLATE(51391-19-6)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-37/38-43
• Safety Statements: 24-37-46
• Hazardous Substances Data: 51391-19-6(Hazardous Substances Data)

Upstream product

• 54116-95-9 methyl hydrogen 2-<(D3)methyl>propanedioate 

Relevant articles and documents

E.S.R. Spectra of Free Radicals Relevant to Methacrylate Polymerization

Carbon-based free radicals were generated by thermal cleavage of the tetraester Me2C(COOMe)-CH2-CMe(COOMe)-CMe(COOMe)-CH2-C(COOMe)Me2 which is a model for head-to-head units in a poly(methyl methacrylate) chain.The resulting electron spin resonance spectrum had higher resolution than the 'nine-line' spectrum previously reported; this enabled identification of the component radicals.In the present case, the spectrum was well matched by a summation of spectra of the Me2C(COOMe)-CH2-CMe(COOMe) radical and the 1-methoxycarbonyl-1-methylethyl radical Me2-C-COOMe derived from it by loss of methyl methacrylate.Both of these radicals were generated in separate experiments.Radicals were also generated from starting materials containing a CD3 group in place of the single CH3.

The synthesis of deuterated methyl methacrylates

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