514196-31-7

Upstream product

• 125411-99-6 ethyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 
• 101966-50-1 2,3,4,6-tetrakis-O-(phenylmethyl)-β-D-galactopyranosyl fluoride 

Relevant academic research and scientific papers

Chemoselective glycosylations of sterically hindered glycosyl acceptors

Unexpected intermolecular aglycon transfer in chemoselective glycosylations between activated thioglycosyl donors and deactivated thioglycosyl acceptors could be avoided by employing a glycosyl acceptor that has a bulky anomeric dicyclohexylmethanethio group. The methodology was applied to the synthesis of a protected fragment of an oligosaccharide released from the jelly coat glycoprotein of X. leavis.