Welcome to LookChem.com Sign In|Join Free
  • or
1-Propanone, 2-hydroperoxy-2-methyl-1-phenyl-, also known as 2-hydroperoxy-2-methyl-1-phenyl-propan-1-one, is an organic compound with the chemical formula C10H12O3. It is a derivative of propanone (acetone), where a hydroperoxy group (-OOH) and a methyl group (-CH3) are attached to the 2-position, and a phenyl group (C6H5) is attached to the 1-position. 1-Propanone, 2-hydroperoxy-2-methyl-1-phenyl- is of interest in the field of organic chemistry, particularly in the study of peroxides and their reactions. It is a colorless liquid with a molecular weight of 180.20 g/mol. Due to the presence of the hydroperoxy group, it is a potentially reactive and sensitive compound, which may require special handling and storage conditions to prevent decomposition or unwanted reactions.

5143-77-1

Post Buying Request

5143-77-1 Suppliers

Recommended suppliers

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

5143-77-1 Usage

Structure

A ketone functional group attached to a peroxide functional group

Type of compound

Ketone peroxide

Uses

Organic synthesis, reagent in various chemical reactions, potential use as a polymerization initiator in the production of plastics and elastomers

Handling precautions

Can be unstable and potentially hazardous if not properly managed.

Check Digit Verification of cas no

The CAS Registry Mumber 5143-77-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,1,4 and 3 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 5143-77:
(6*5)+(5*1)+(4*4)+(3*3)+(2*7)+(1*7)=81
81 % 10 = 1
So 5143-77-1 is a valid CAS Registry Number.

5143-77-1Downstream Products

5143-77-1Relevant academic research and scientific papers

Competitive Desulfonylative Reduction and Oxidation of α-Sulfonylketones Promoted by Photoinduced Electron Transfer with 2-Hydroxyaryl-1,3-dimethylbenzimidazolines under Air

Hasegawa, Eietsu,Nakamura, Shyota,Oomori, Kazuki,Tanaka, Tsukasa,Iwamoto, Hajime,Wakamatsu, Kan

, p. 2556 - 2569 (2021/02/27)

Desulfonylation reactions of α-sulfonylketones promoted by photoinduced electron transfer with 2-hydroxyarylbenzimidazolines (BIH-ArOH) were investigated. Under aerobic conditions, photoexcited 2-hydroxynaphthylbenzimidazoline (BIH-NapOH) promotes competitive reduction (forming alkylketones) and oxidation (producing α-hydroxyketones) of sulfonylketones through pathways involving the intermediacy of α-ketoalkyl radicals. The results of an examination of the effects of solvents, radical trapping reagents, substituents of sulfonylketones, and a variety of hydroxyaryl- and aryl-benzimidazolines (BIH-ArOH and BIH-Ar) suggest that the oxidation products are produced by dissociation of α-ketoalkyl radicals from the initially formed solvent-caged radical ion pairs followed by reaction with molecular oxygen. In addition, the observations indicate that the reduction products are generated by proton or hydrogen atom transfer in solvent-caged radical ion pairs derived from benzimidazolines and sulfonylketones. The results also suggest that arylsulfinate anions arising by carbon-sulfur bond cleavage of sulfonylketone radical anions act as reductants in the oxidation pathway to convert initially formed α-hydroperoxyketones to α-hydroxyketones. Finally, density functional theory calculations were performed to explore the structures and properties of radical ions of sulfonylketones as well as BIH-NapOH.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1 Customer Service

What can I do for you?
Get Best Price

Get Best Price for 5143-77-1