51439-03-3

Upstream product

• 17746-05-3 undecanoyl chloride 
• 131973-46-1 benzyltetrabutyl stiborane 
• 863913-26-2 1-Methyl-4-(2-methylsulfanyl-1-phenyl-dodecane-2-sulfonyl)-benzene 
• 872-05-9 1-Decene 
• 64-04-0 phenethylamine 
• 1589-82-8 phenylmagnesium bromide 
• 1724-39-6 cyclododecanol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 6175-49-1 dodecan-2-one 
• 830-13-7 cyclododecanone 
• 32400-09-2 1-methylcyclododecanol 
• 103763-35-5 cyclododecyl methanesulfonate 
• 87657-55-4 p-tolyl undecyl sulfone 
• 693-67-4 bromoundecane 

Relevant academic research and scientific papers

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides were converted to the corresponding carbonyl or imine compounds without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction.

C-H and C-C bond activation of primary amines through dehydrogenation and transimination

Matrix presented Dehydrogenation and subsequent transimination of primary amines offer a new pathway for C-H bond activation, ortho-alkylation, and C-C bond activation to afford a variety of ketones in the reaction of 1-alkene by a cocatalyt system of Rh(I) and 2-amino-3-picoline.

A Convenient Method for the Synthesis of Acyclic Ketones. Synthesis of Sex Pheromone of Douglas Fir Tussock Moth

(α-Alkyl-α-methylthio)alkyl p-tolyl sulfones derived from the reaction of a-alkylated alkyl p-tolyl sulfones with dimethyl disulfide could be easily hydrolyzed by CuCl2-SiO2 to give the corresponding ketones in fairly good yields.This method was applied to the synthesis of Douglas Fir Tussock Moth Pheromone.