51439-83-9Relevant academic research and scientific papers
Palladium-Catalyzed Direct Acylation: One-Pot Relay Synthesis of Anthraquinones
Suchand, Basuli,Satyanarayana, Gedu
, p. 769 - 779 (2019)
A bis-acylation strategy to access functionalized anthraquinones via one-pot relay process, is presented. The first acylation was feasible under [Pd]-catalyzed intermolecular direct acylation reaction, while, the second acylation was accomplished by using intramolecular Friedel-Crafts acylation. Notably, benchtop aldehydes have been utilized as non-toxic acylation agents in the key [Pd]-catalyzed acylation.
