51440-20-1Relevant academic research and scientific papers
Hydrosilylation of Carbonyls Catalyzed by Hydridoborenium Borate Salts: Lewis Acid Activation and Anion Mediated Pathways
Rawat, Sandeep,Bhandari, Mamta,Porwal, Vishal Kumar,Singh, Sanjay
supporting information, p. 7195 - 7203 (2020/05/18)
The electronically unsaturated three-coordinated hydridoborenium cations [LBH]+[HB(C6F5)3]-(1) and [LBH]+[B(C6F5)4]-(2), supported by a bis(phosphinimino)amide ligand, were found to be excellent catalysts for hydrosilylation of a range of aliphatic and ar
Selective alkyl ether cleavage by cationic bis(phosphine)iridium complexes
Jones, Caleb A. H.,Schley, Nathan D.
, p. 1744 - 1748 (2019/02/20)
Catalysts capable of heterolytic silane activation have been successfully applied to the conversion of alkyl ethers to silyl ethers via C-O bond cleavage. The previously-reported cationic pincer-supported iridium complex for this transformation suffers fr
A convenient and efficient rhenium-Catalyzed hydrosilylation of ketones and aldehydes
Dong, Hailin,Berke, Heinz
experimental part, p. 1783 - 1788 (2011/02/25)
The easily available rhenium(I) complex [Re(CH3CN) 3Br2(NO)] catalyzes the homogeneous hydrosilylation of a great variety of organic carbonyl compounds (ketones and aldehydes). The reaction is quite sensitive to the solven
