5153-72-0Relevant academic research and scientific papers
Geometrically Selective Denitrative Trifluoromethylthiolation of β-Nitrostyrenes with AgSCF3for (E)-Vinyl Trifluoromethyl Thioethers
Fang, Ge,Hong, Jianquan,Huang, Shuai,Jiang, Chao,Liu, Yang,Zhang, Wei,Zheng, Changge
, (2020)
An efficient copper(II)-promoted denitrative trifluoromethylthiolation under mild reaction conditions has been developed for vinyl trifluoromethyl thioethers to construct Cvinyl-SCF3 bonds with stable AgSCF3 as a source of the trifluoromethylthio. This reaction system tolerates a broad range of functional groups to commendably achieve a high product yield and excellent stereoselectivity of E/Z.
Visible-Light-Promoted Cross-Coupling of N-Alkylpyridinium Salts and Nitrostyrenes
Ferko, Branislav,Mar?eková, Michaela,Detková, Katarína Ráchel,Doháňo?ová, Jana,Berke?, Du?an,Jakubec, Pavol
supporting information, p. 8705 - 8710 (2021/11/20)
A stereoselective, denitrative cross-coupling of β-nitrostyrenes with N-alkylpyridinium salts for the preparation of functionalized styrenes has been developed. The visible-light-induced reaction proceeds without any catalyst at ambient temperature. Broad in scope and tolerant to multiple functional groups, the moderately yielding transformation is orthogonal to several traditional metal-catalyzed cross-couplings.
DETERMINATION OF THE CRYSTAL STRUCTURE OF 4-IODO-β-NITROSTYRENE WITH THE AID OF PACKING CONSIDERATIONS: A STUDY OF HALOGEN...NITRO INTERACTIONS
Desiraju, G. R.,Pedireddi, V. R.,Sarma, J. A. R. P.,Zacharias, D. E.
, p. 451 - 466 (2007/10/02)
4-Iodo-β-nitostyrene forms crystals which are not satisfactory for the collection of X-ray diffraction data.However, it was possible to obtain an approximate unit cell and to record the X-ray powder spectrum.This information coupled with a knowledge of th
