51533-74-5Relevant academic research and scientific papers
The Nature of Electronic Interactions Governing the Control of Π-Facial Selectivity in the Capture of 5-Substituted(X)-2-Adamantyl Radicals: Electrostatic versus Hyperconjugative Effects
Adcock, William,Clark, Christopher I.,Trout, Neil A.
, p. 297 - 300 (1994)
An electrostatic rather than a hyperconjugative effect appears to be the dominant factor governing the control of Π-facial selectivity in the capture of 5-substituted(X)-2-adamantyl radicals.
Estimation of Electron-Transfer Contributions in Reactions of Alkyl Bromides with (Trimethyltin)sodium
Kuivila, Henry G.,Smith, Gary F.
, p. 2918 - 2919 (2007/10/02)
Estimates of the minimum degrees of electron-transfer contributions to the mechanisms of reaction of primary, secondary, and tertiary bromides with (trimethyltin)sodium have been obtained by the use of dicyclohexylphosphine as a free-radical trap.
