51534-37-3Relevant articles and documents
A short synthesis of an acetylenic alcohol from the sponge cribrochalina vasculum
Gung, Benjamin W.,Dickson, Hamilton D.,Seggerson, Sara,Bluhm, Kristin
, p. 2733 - 2740 (2002)
A short synthesis of the acetylenic alcohol from cribrochalina vasculum is described. No protecting groups are used in this synthesis. The key step is an enzymatic resolution of a racemic mixture of the title compound.
A Facile and Highly Stereoselective Synthesis of Trichonine by Two Consecutive Reactions of Arsonium Salts
Shi, Lilan,Yang, Jianhua,Li, Ming,Huang, Yao-Zeng
, p. 377 - 378 (2007/10/02)
Trichonine (5) has been synthesized from 1-hexadecanal (1) by two steps of consecutive olefination, in which formylmethyltriphenylarsonium bromide (2) and (pyrrolidinecarbonyl)methyltriphenylarsonium bromide (4) were used in the presence of potassium carbonate.The product was obtained in pure (2E,4E) configuration, and the overall yield reached 87percent.
Chemical synthesis of long chain 2 alkynals, alkynols, 2c and 2t alkenals and 2c and 2t alkenols
Stoffel,Melzner
, p. 1626 - 1632 (2007/10/12)
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