51537-82-7Relevant academic research and scientific papers
Asymmetric synthesis of (S)-β2-homoarylglycines
Calmes, Monique,Escale, Francoise,Glot, Christele,Rolland, Marc,Martinez, Jean
, p. 2459 - 2466 (2007/10/03)
The synthesis of racemic N-phthalyl β2-homoarylglycines 5 and their asymmetric transformation have been investigated. The key step is the stereoselective addition of the (R)-pantolactone to the corresponding prochiral ketene 7.
NEW METHODS AND REAGENTS IN ORGANIC SYNTHESIS, 8. TRIMETHYLSILYLDIAZOMETHANE, A NEW, STABLE, AND SAFE REAGENT FOR THE CLASSICAL ARNDT-EISTERT SYNTHESIS
Aoyama, Toyohiko,Shioiri, Takayuki
, p. 4461 - 4462 (2007/10/02)
Stable and safe trimethylsilyldiazomethane (TMSCHN2) can be used efficiently for the Arndt-Eistert synthesis in place of highly toxic and explosive diazomethane.
