51590-64-8Relevant articles and documents
NICKEL(II) INDUZIERTE C-C VERKNUEPFUNG ZWISCHEN KOHLENMONOXID UND ALKINEN UNTER ERHALT DER DREIFACHBINDUNG
Hoberg, Heinz,Riegel, Hans Josef
, p. 245 - 250 (2007/10/02)
Acetylene and 1-alkynes react with carbon monoxide under basic conditions (amines) with nickel(II) complexes, L2NiBr2 (L=Et2NH, (C6H5)3P), to give acetylencarboxamides with maintenance of the triple bond.Intermediates are isolated, characterised and a mechanism is proposed.