51596-01-1

Usage

Physical state

Colorless liquid

Odor

Strong ammonia-like

Flammability

Highly flammable

Toxicity

Highly toxic

Usage

Rocket propellant, fuel in spacecraft propulsion systems

Hypergolic property

Ignites upon contact with an oxidizer

Additional uses

Specialty chemical in the production of pharmaceuticals and agricultural chemicals

Health hazards

Skin and eye irritation, respiratory issues, neurological effects

Hazardous substance

Yes, precautions should be taken when handling or using

Environmental impact

Potentially harmful to the environment due to its toxicity and flammability

Upstream product

• 932-96-7 N-methyl(p-chloroaniline) 

Relevant academic research and scientific papers

Iodine-mediated oxidative N-N coupling of secondary amines to hydrazines

An I2-mediated N-N coupling reaction has been established for oxidative dimerization of N-aryl aminopyridines to a variety of novel hydrazine derivatives under mild conditions. This synthetic method does not require use of transition metals and

Transition-Metal-Free Dehydrogenative N–N Coupling of Secondary Amines with KI/KIO4

A transition-metal-free method for the dehydrogenative N–N coupling of secondary amines has been accomplished. This oxidative KI/KIO4 protocol is mild and operationally simple. A diverse range of diphenylamines, carbazoles, and N-alkylanilines readily undergo N–N homo-coupling effectively. Notably, the N–N cross-coupling of two different arylamines is also demonstrated, which provides a straightforward approach to the complex N–N structures.

A dehydrogenative homocoupling reaction for the direct synthesis of hydrazines from N-alkylanilines in air

A copper-catalyzed N-N bond-forming reaction was performed by a dehydrogenative homocoupling of N-alkylanilines, affording N,N-dialkyl-N,N- diphenylhydrazines in 72-88% yields. This new strategy has the advantages of direct synthesis from N-alkylanilines,