516457-75-3

Basic information

• Product Name: tert-Butyl-[(2S,3S,5S)-5-{(3Z,6Z)-3-chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-dimethyl-silane
• Synonyms: tert-Butyl-[(2S,3S,5S)-5-{(3Z,6Z)-3-chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-dimethyl-silane
• CAS NO: 516457-75-3
• Molecular Weight: 797.547
• Mol File: 516457-75-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-Butyl-[(2S,3S,5S)-5-{(3Z,6Z)-3-chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-[(2S,3S,5S)-5-{(3Z,6Z)-3-chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-dimethyl-silane(516457-75-3)
• EPA Substance Registry System: tert-Butyl-[(2S,3S,5S)-5-{(3Z,6Z)-3-chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-dimethyl-silane(516457-75-3)

Safety Data

• Hazardous Substances Data: 516457-75-3(Hazardous Substances Data)

Upstream product

• 14470-28-1 mono-4-methoxytrityl chloride 
• 516457-60-6 (2Z,5Z)-8-[(2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-2-yl]-6-chloro-2-methyl-octa-2,5-dien-1-ol 
• 516457-54-8 tert-Butyl-[(2S,3S,5S)-5-[(Z)-3-chloro-6-(tetrahydro-pyran-2-yloxy)-hex-3-enyl]-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-dimethyl-silane 
• 516457-58-2 (2Z,5Z)-8-[(2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-2-yl]-6-chloro-2-methyl-octa-2,5-dienoic acid methyl ester 
• 516457-56-0 (Z)-6-[(2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-2-yl]-4-chloro-hex-3-en-1-ol 
• 516457-48-0 2-[(2S,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-2-yl]-ethanol 
• 516457-47-9 [(2R,4S,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-2-yl]-acetic acid methyl ester 
• 516457-38-8 [(2S,3S,5R)-5-(2-Bromo-ethyl)-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yloxy]-tert-butyl-dimethyl-silane 
• 516457-41-3 (4S,5S)-4-(2-Methanesulfinyl-2-methylsulfanyl-ethyl)-5-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxolane 
• 1055029-57-6 (E)-(5S,6S)-5,6-Dihydroxy-7-(4-methoxy-benzyloxy)-hept-2-enoic acid methyl ester 
• 516457-86-6 (4R,5S)-4-Iodomethyl-5-(4-methoxy-benzyloxymethyl)-2,2-dimethyl-[1,3]dioxolane 
• 516457-43-5 (2S,3S)-5-Methoxy-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-ol 
• 118620-86-3 (2S,3S)-4-(p-methoxybenzyloxy)-2,3-(isopropylidenedioxy)-butan-1-ol 

Downstream Products

• 516457-79-7 Bromo-acetic acid (2S,3S,5S)-5-{(3Z,6Z)-3-chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yl ester 
• 516457-80-0 Bromo-acetic acid (2S,3S,5S)-5-((3Z,6Z)-3-chloro-8-hydroxy-7-methyl-octa-3,6-dienyl)-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yl ester 
• 516457-30-0 Bromo-acetic acid (2S,3S,5S)-5-((3Z,6Z)-3-chloro-7-methyl-8-oxo-octa-3,6-dienyl)-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-yl ester 
• 516457-77-5 (2S,3S,5S)-5-{(3Z,6Z)-3-Chloro-8-[(4-methoxy-phenyl)-diphenyl-methoxy]-7-methyl-octa-3,6-dienyl}-2-(4-methoxy-benzyloxymethyl)-tetrahydro-furan-3-ol 

Relevant articles and documents

Enantioselective synthesis of 15-epi-haterumalide NA methyl ester and revised structure of haterumalide NA

(Matrix presented). The enantioselective synthesis of the enantiomer of the haterumalide NA methyl ester, a cytotoxic macrolide from an Okinawan sponge, was achieved from the threitol derivative in 26 steps. The key steps are the stereoselective construct