51703-79-8Relevant academic research and scientific papers
S-Methyl diethylthiophosphinate in mono- and di(dechloromethylthioylation) of substituted benzylidene chlorides
Gazizov,Valieva,Ivanova, S. Yu.,Khairullin,Kirillina, Yu. S.,Khairullina,Ibragimov, Sh. N.
, p. 1889 - 1892 (2019/10/22)
The main route of a new reaction of (dichloromethyl)arenes with S-methyl diethylthiophosphinate is the attack of the thiol sulfur atom (P–SMe) on the methylene carbon atom. A new method for synthesizing dimethyl dithioacetals of arenecarbaldehydes without
Reactions of Benzylidene Chlorides with S-Methyl Diethylphosphinothioate
Gazizov,Valieva,Ivanova, S. Yu.,Karimova,Khairullin,Gazizova
, p. 2386 - 2389 (2020/02/25)
S-Methyl diethylphosphinothioate reacted with benzylidene chlorides to give the corresponding aryl(chloro)methyl methyl sulfide and diethylphosphinoyl chloride. The product structure suggests initial attack of the methylsulfanyl group on the CH carbon ato
REACTIONS OF 2,4,6-TRIARYL-DIHYDRO-1,3,5-DITHIAZINES WITH ELECTROPHILIC REAGENTS
Takikawa, Yuji,Shimada, Kazuaki,Makabe, Takahiro,Takizawa, Saburo
, p. 1503 - 1506 (2007/10/02)
2,4,6-Triaryl-dihydro-1,3,5-dithiazines reacted with electrophilic reagents such as p-TsOH*H2O, CF3COOH, HCl, and BF3*OEt2 under reflux in CH3CN to afford α-2,4,6-triaryl-1,3,5-trithianes and β-isomers (3a-d) in good yields.Reaction with I2 gave selectively 3a-d in high yields, while with ICl or IBr gave 3a-d and p-substituted benzylideneamine*HY.
