5171-98-2Relevant academic research and scientific papers
The synthesis of 1,2-diarylindenes via DDQ-mediated dehydrogenative intramolecular cyclization
Li, Yi,Cao, Li,Luo, Xiaoyan,Deng, Wei-Ping
, p. 5974 - 5979 (2015/03/30)
A direct DDQ-mediated dehydrogenative intramolecular cyclization of (Z)-1,2,3-triaryl substituted propylenes promoted by Cu(OAc)2 was developed, providing 1,2-diarylindene derivatives in moderate to good yields (up to 92%) under mild conditions
Advantageous Syntheses of Diazo Compounds by Oxidation of Hydrazones with Lead Tetraacetate in Basic Environments
Holton, Terrence L.,Shechter, Harold
, p. 4725 - 4729 (2007/10/02)
Varied sensitive diazo compounds 3 are produced efficiently and safely in 3-6 g quantities by oxidation (eq 1) of hydrazones 1 at -78 deg C with lead tetraacetate (2) in triethylamine/chloroform, N-methylmorpholine/dimethylformamide, tetramethylguanidine (8)/dimethylformamide, and tetramethylguanidine/methylene chloride, respectively, upon use of appropriate workup and handling techniques.New and improved nonhazardous procedures have been developed for preparing and handling hydrazones 1 from aldehydes and ketones in reactions with excess hydrazine.
