51733-68-7Relevant academic research and scientific papers
Stereochemistry of an Ene Reaction involving 1,7-Dienes; Bicyclononanes from (3-Cyclohexenyl)diallylcarbinols
Thomas, Alan F.,Lander-Schouwey, Marina
, p. 191 - 200 (2007/10/02)
(3-Cyclohexenyl)diallylcarbinols undergo a thermal retro-ene reaction to give crotonylcyclohexenes at ca. 200 degC.A side-reaction is an ene reaction to give bicyclononanes.These become the main products above 300 degC.The stereochemistry of 2-allyl-1,4,6-trimethylbicyclo-6-nonen-2-ols and related compounds is discussed, and a case is described in which the allyl group is not freely rotating.
PALLADIUM DICHLORIDE-PROMOTED CYCLIZATIONS OF 1,5-DIENES. A NEW METHOD FOR FORMING CYCLOHEXENES.
Overman, Larry E.,Renaldo, Alfred F.
, p. 2235 - 2238 (2007/10/02)
1,5-Hexadienes, which are substituted with electron-withdrawing groups at carbon-3, undergo regioselective rearrangement to cyclohexenes upon treatment with palladium dichloride.
