51768-80-0

Upstream product

• 51768-77-5 Dimethyl-[(E)-3-(2,6,6-trimethyl-cyclohex-2-enyl)-allyl]-amine 
• 51768-74-2 butyl (2E)-3-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-propenoate 
• 51768-75-3 (E)-3-(2,6,6-trimethylcyclohex-2-enyl)prop-2-en-1-ol 
• 127-41-3 alpha-ionone 
• 14505-74-9 α-cyclocitral 
• 1826-67-1 vinyl magnesium bromide 
• 51768-78-6 N,N-Dimethyl-O-[1-(2,6,6-trimethyl-cyclohex-2-enyl)-allyl]-hydroxylamine 

Downstream Products

• 51768-79-7 6-propenoyl-1,5,5-trimethyl-1-cyclohexene 

Relevant academic research and scientific papers

Effect of tether length on Ti(III)-mediated cyclization of epoxyalkenes and unsaturated epoxyketones

The chemo- and regioselectivity of the radical cyclization induced by titanocene chloride of a series of epoxyalkenes and another of unsaturated epoxyketones are investigated. 5-Exo and 6-exo cyclizations are the main processes with epoxyalkenes. 3-Exo and 4-exo cyclizations onto the carbonyl group and 6-exo and 8-endo onto the carbon-carbon double bond are the preferred processes with epoxyenones. A tandem reaction, 6-exo onto C=C, followed by a 3-exo onto C=O, and a disfavored 5-endo cyclization onto C=C are reported.