51770-84-4Relevant academic research and scientific papers
P -Selective (sp2)-C-H functionalization for an acylation/alkylation reaction using organic photoredox catalysis
Pandey, Ganesh,Tiwari, Sandip Kumar,Singh, Bhawana,Vanka, Kumar,Jain, Shailja
, p. 12337 - 12340 (2017/11/20)
p-Selective (sp2)-C-H functionalization of electron rich arenes has been achieved for acylation and alkylation reactions, respectively, with acyl/alkylselenides by organic photoredox catalysis involving an interesting mechanistic pathway.
THE VINYLATION OF ARENES WITH 1-(PHENYLTHIO)VINYLSTANNANES
Takeda, Takeshi,Kanamori, Fumio,Masuda, Mitsutoshi,Fujiwara, Tooru
, p. 5567 - 5570 (2007/10/02)
The vinylation of arenes using 1-(phenylthio)vinylstannanes proceeded in the presence of tin(IV) chloride and molecular sieves 4A to afford 1-arylalkenyl sulfides in good yields.The stereochemistry of the olefinic moiety was determined after oxidation to the corresponding sulfones and it was found that the present reaction gave the thermodynamically stable stereoisomers.
