51793-09-0

Basic information

• Product Name: 4-Methyl-N-phenylnaphthalen-1-aMine
• Synonyms: 4-Methyl-N-phenylnaphthalen-1-aMine
• CAS NO: 51793-09-0
• Molecular Formula: C₁₇H₁₅N
• Molecular Weight: 233.3077
• Mol File: 51793-09-0.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Methyl-N-phenylnaphthalen-1-aMine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methyl-N-phenylnaphthalen-1-aMine(51793-09-0)
• EPA Substance Registry System: 4-Methyl-N-phenylnaphthalen-1-aMine(51793-09-0)

Safety Data

• Hazardous Substances Data: 51793-09-0(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 86-52-2 1-Chloromethylnaphthalene 
• 4523-45-9 1-amino-4-methylnaphthalene 

Downstream Products

• 10567-95-0 6,10-Dimethyl-7,8-benzacridin 

Relevant articles and documents

Palladium-Catalyzed Highly Regioselective Aromatic Substitution of Benzylic Ammonium Salts with Amines

An unprecedented aromatic substitution reaction of benzylic ammonium salts has been developed through palladium-catalyzed C-N bond cleavage. A range of primary and secondary amines participated in a palladium-catalyzed aromatic substitution reaction of benzylic ammonium salts, delivering sterically hindered aromatic amines in moderate to excellent yields with extremely high regioselectivity. Preliminary mechanistic studies permitted successful identification of Π-benzylpalladium complexes and Γ-vinyl allylic amines as key intermediates. This study paves the way for the use of benzylic ammonium salts in the aromatic substitution reactions.