51862-24-9

Basic information

• Product Name: chloroacetylferrocene
• Synonyms: chloroacetylferrocene
• CAS NO: 51862-24-9
• Molecular Formula: C₁₂H₁₁ClFeO
• Molecular Weight: 0
• Mol File: 51862-24-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: chloroacetylferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: chloroacetylferrocene(51862-24-9)
• EPA Substance Registry System: chloroacetylferrocene(51862-24-9)

Safety Data

• Hazardous Substances Data: 51862-24-9(Hazardous Substances Data)

Upstream product

• 102-54-5 ferrocene 
• 79-04-9 chloroacetyl chloride 

Downstream Products

• 1271-51-8 vinyl ferrocene 
• 1189128-56-0 1-ferrocenyl-2-[3-(methoxyphenyl)thio]ethanone 
• 1353572-83-4 2-oxo-2-ferrocenylethyl 2-(4-methoxyphenyl)acetate 
• 1236188-39-8 1-ferrocenyl-2-(3-(4-nitrophenyl)-1H-1,2,4-triazol-5-ylthio)ethanone 
• 1236188-37-6 1-ferrocenyl-2-(3-(3-bromophenyl)-1H-1,2,4-triazol-5-ylthio)ethanone 
• 1236188-36-5 1-ferrocenyl-2-(3-(4-methoxyphenyl)-1H-1,2,4-triazol-5-ylthio)ethanone 
• 1236188-35-4 1-ferrocenyl-2-(3-p-tolyl-1H-1,2,4-triazol-5-ylthio)ethanone 
• 1236188-34-3 1-ferrocenyl-2-(3-phenyl-1H-1,2,4-triazol-5-ylthio)ethanone 
• 933037-49-1 (C2H5)(C(p-trimethylacetoxyphenyl))2OCH2CO[(η5-C5H4)FeCp] 
• 179803-88-4 9-[4-(1-ferrocenoylmethoxy)phenyl]-10-(4-methoxyphenyl)anthracene 

Relevant articles and documents

Synthesis of ferrocenyl-1,2-diketones and related compounds: Crystal and molecular structures of 1,2-diferrocenylethanedione and 1-ferrocenyl-2-(4-biphenylyl) ethanedione

Ferrocenyl-1,2-diketones FcCOCOR, 3, [Fc = (C5H5)Fe(C5H4)] can be prepared by oxidation of acylferrocenes FcCOCH2R or, more efficiently, by oxidation of the isomeric ketones FcCH2COR, 2. The ketones 2 are in turn readily synthesized from the salt (FcCH2PPh3)+I- via the acylated salts [FcCH(COR)PPh3]+I-. The haloacylferocenes FcCOCClxH3-x (x = 1, 2, 3, of which the x = 2 example is synthetically equivalent to a diketone) are synthesized by Friedel-Crafts acylation of ferrocene using CClxH3-xCOCl/AlCl3, but the reaction proceeds via two parallel pathways, one giving the normal acyl derivatives FcCOCClxH3-x and the other giving the reduced products FcCOCClx-1H4-x. Two diketones FcCOCOFc 3b and FcCOCOC6H4Ph 3c have been structurally characterised by single-crystal X-ray diffraction.