51873-57-5Relevant articles and documents
Palladium-Catalyzed Aerobic Oxidative Cyclization of Aliphatic Alkenyl Amides for the Construction of Pyrrolizidine and Indolizidine Derivatives
Lo, Kai-Yip,Ye, Liu,Yang, Dan
supporting information, p. 1570 - 1575 (2017/08/11)
An efficient palladium-catalyzed aerobic oxidative cyclization has been developed to synthesize a variety of pyrrolizidine and indolizidine derivatives from simple aliphatic alkenyl amides in moderate to good yields. The reaction features the capability of accessing various N-heterocycles and the use of molecular oxygen (1 atm) as the green oxidant.
Transfer hydrogenation of α-branched ketimines: Enantioselective synthesis of cycloalkylamines via dynamic kinetic resolution
Ros, Abel,Magriz, Antonio,Dietrich, Hansjoerg,Ford, Mark,Fernandez, Rosario,Lassaletta, Jose M.
, p. 1917 - 1920 (2007/10/03)
The transfer hydrogenation of 2-substituted bicyclic and monocyclic ketimines using HCO2H/Et3N as the hydrogen source and TsDPEN-based Ru(II) and Ir(III) catalysts proceeds with dynamic kinetic resolution to afford the corresponding