51945-87-0Relevant academic research and scientific papers
N-BROMOURETHANE IN REACTION WITH TRICHLOROETHYLENE
Drozdova, T. I.,Mirskova, A. N.,Levkovkaya, G. G.
, p. 862 - 865 (2007/10/02)
The reaction of N-bromourethane with trichloroethylene leads to the formation of 2-bromo-2,2-dichloro-1,1-di(ethoxycarbonylamino)ethane.A reaction mechanism including a series of consecutive transformations is proposed: Disproportionation of the N-bromourethane to N,N-dibromourethane and urethane; reaction of the N,N-dibromourethane with trichloroethylene with the formation of N-(2-bromo-2,2-dichloroethylidene)ethoxycarbonylamine; addition of urethane to the latter with the formation of 2-bromo-2,2-dichloro-1,1-di(ethoxycarbonylamino)ethane.
