5202-73-3Relevant academic research and scientific papers
Effect of micellar medium on photoannelation vs energy transfer in the system excited cyclohex-2-en-1-one-cyclopentadiene
Kumar, M. Suresh,Rao, Jampani Madhusudana
, p. 5383 - 5388 (2007/10/02)
The relative ratio of enone-CPD adducts and C15H18 formed in the photochemical reaction between cyclohex-2-en-1-one and its 4,4 dimethyl derivative and CPD in different media suggest that an exciplex is responsible for 2+2 photoannelation and energy transfer and a transoid or twisted enone for photo Diels-Alder reaction.
anti--Dicyclopentadiene
Grimme, Wolfram,Schumachers, Lothar,Roth, Wolfgang R.,Breuckmann, Rolf
, p. 3197 - 3208 (2007/10/02)
The synthesis of anti-tricyclo2,5>deca-3,7-diene (2) starting from the -cycloadduct 4a derived from cyclopentadiene and tropon is described.Compound 2 decomposes at 200 deg C yielding a mixture of cyclopentadiene (12), endo--dicyclopentadiene (13), anti-cis--dicyclopentadiene (14) and the cyclopentenyl-cyclopentadienes 15 and 16.The formation of a common diradical intermediate 11 in the decomposition of 2, 13 and 14 has been sought by means of the kinetic analyses of these reactions.
