52088-08-1

Basic information

• Product Name: 9-(2,6-diisopropylphenolato)-9-borabicyclononane
• CAS NO: 52088-08-1
• Molecular Weight: 298.277
• Mol File: 52088-08-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-(2,6-diisopropylphenolato)-9-borabicyclononane(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(2,6-diisopropylphenolato)-9-borabicyclononane(52088-08-1)
• EPA Substance Registry System: 9-(2,6-diisopropylphenolato)-9-borabicyclononane(52088-08-1)

Safety Data

• Hazardous Substances Data: 52088-08-1(Hazardous Substances Data)

Upstream product

• 76448-06-1 potassium 9,9-dihydrido-9-boratabicyclononane 
• 1303613-03-7 methyltris(2,6-diisopropylphenolato)titanium 
• 21205-91-4 9-borabicyclo[3.3.1]nonane dimer 
• 2078-54-8 2,6-diisopropylphenol 

Relevant articles and documents

Tris(2,6-diisopropylphenolato)titanium(IV) dihydridodiorganylborates: Synthesis and structures

The reactions of tris(2,6-diisopropylphenolato)titanium(IV) chloride with alkali-metal dihydridodiorganylborates M(H2BR2) (M = Li, K; R = Me, C6H11, CMe3; BR2 = BC5H10, BC8H14) led to the corresponding titanium dihydridodiorganylborates. However, in almost all cases byproducts such as (2,6-diisopropylphenolato)diorganylboranes, triorganylboranes, diorganylboranes, diborane and tetrakis(2,6- diisopropylphenolato)titanium(IV) were also generated. (2,6-iPr 2C6H3O)3Ti(H2BR 2) compounds also resulted from the interaction of methyltris(2,6-diisopropylphenolato)titanium, for example, with catecholborane. In addition to the formation of tris(2,6-diisopropylphenolato) catecholboratotitanium(IV), B-methylcatecholborane was also formed The reaction of potassium dihydro-9-cyclooctylborate with 2,6-bis(2,2-di-tert-butyl-2- hydroxyethyl)pyridinetitanium dichloride (LTiCl2) led to the complex LTi(H2BC8H14)2. This compound showed no agostic C-H···Ti interaction in contrast to (2,6-iPr2C6H3O)3TiH 2BC8H14 and the corresponding titanium dihydridobis(cyclohexyl)borate.