52183-77-4

Basic information

• Product Name: 1,5-Cyclohexadiene-1-carboxylic acid, 3,4-dihydroxy-, methyl ester, (3R,4R)-rel-
• CAS NO: 52183-77-4
• Molecular Formula: C8H10O4
• Molecular Weight: 170.165
• Mol File: 52183-77-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,5-Cyclohexadiene-1-carboxylic acid, 3,4-dihydroxy-, methyl ester, (3R,4R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Cyclohexadiene-1-carboxylic acid, 3,4-dihydroxy-, methyl ester, (3R,4R)-rel-(52183-77-4)
• EPA Substance Registry System: 1,5-Cyclohexadiene-1-carboxylic acid, 3,4-dihydroxy-, methyl ester, (3R,4R)-rel-(52183-77-4)

Safety Data

• Hazardous Substances Data: 52183-77-4(Hazardous Substances Data)

Upstream product

• 17791-32-1 7-Oxabicyclo<2.2.1>hept-5-en-2-carbonsaeure-methylester 
• 88517-53-7 cis-exo-2,3-dihydroxy-6-methoxycarbonyl-7-oxabicycloheptane 
• 88517-54-8 (1S,2S,6R,7R)-4,4-Dimethyl-3,5,10-trioxa-tricyclo[5.2.1.0^2,6]decane-8-carboxylic acid methyl ester 
• 92830-74-5 (+/-)-methyl 4,5-O,O-isopropylidine-4α,5α-dihydroxycyclohexen-3-one-1-carboxylate 
• 88165-26-8 (+/-)-3,4-O,O-isopropylidine-1-methoxycarbonyl-3α,4α,5α-trihydroxycyclohexene 
• 88517-55-9 (+/-)-methyl 5,6-O,O-isopropylidinecyclohexa-1,3-diene-2-carboxylate 

Relevant articles and documents

REACTIVITY STUDIES IN THE SHIKIMIC ACID SERIES: THE SYNTHESIS OF RACEMIC METHYL 6α-FLUOROSHIKIMATE

The regio- and stereo-selective epoxidation of methyl 3,4-dihydrobenzoate derivatives has been investigated.Perbenzimidic acid leads only to epoxides formed at the Δ1,2 bond.More electrophilic reagents such as MCPBA also give products of this t

BRIEF SYNTHESES OF (+/-)-METHYL SHIKIMATE, (+/-)-METHYL EPISHIKIMATE AND STRUCTURAL VARIANTS

Two brief syntheses of (+/-)-methyl shikimate are described in a strategy which offers potentially flexible access to a range of analogues.New intramolecular rearrangement reactions of epoxides derived from methyl 7-oxabicyclohept-3-ene 6-carboxylate and methyl bicyclohept-3-ene 6 carboxylate are described.