52196-03-9Relevant academic research and scientific papers
Chemistry of Polyfunctional Ligands, 60 On Cage Compounds with the Heteroelements Arsenic and Selenium
Ellermann, Jochen,Lietz, Martin
, p. 1514 - 1517 (2007/10/02)
The reaction of 1,1,1-tris(diiodoarsinomethyl)ethane, CH3C(CH2AsI2)3 (1) with NaAs(C6H5)2 in the molar ratio of 1:3 gives 4-methyl-1,2,6-triarsa-tricyclo2,6>-heptane, CH3C(CH2As)3 (2).The previously synthesized CH3C(CH2AsS)3 (4) can be desulphurated with triphenylphosphine to yield also 2.The reaction of 1 with NaSeH gives the new cage compound 6-methyl-1,3,4-triarsa-2,8-diselena-tricyclo3,4>-nonane, CH3C(CH2As)3Se2 (5). - Keywords: Hetero Cage Compounds, Synthesis, Vibrational Spectra, Mass Spectra, 1H NMR Spectra
