522607-44-9Relevant academic research and scientific papers
(η6-arene)RuII/chiral SN ligand: A novel bifunctional catalyst system for asymmetric transfer hydrogenation of aromatic ketones
Ito, Masato,Shibata, Yuji,Watanabe, Akira,Ikariya, Takao
experimental part, p. 1621 - 1626 (2009/12/24)
A binary catalyst system of [RuCl2(η6-arene)] 2 and a protic aminothiol (SN) ligand has been found to promote hydrogen transfer between alcohols and carbonyl compounds. The chiral catalyst system with the pipecolinol-derived chiral SN ligand displays excellent stereoselectivity in the asymmetric transfer hydrogenation of aromatic ketones using HCO2H-Et3N. Novel unsymmetrical bis(thiolate)- bridged binuclear complex, which is relevant to the generation of catalytically active species, has been synthesized and structurally characterized. Georg Thieme Verlag Stuttgart.
Efficient synthesis of primary 2-aminothiols from 2-aminoalcohols and methyldithioacetate
Mercey, Guillaume,Brégeon, Delphine,Gaumont, Annie-Claude,Levillain, Jocelyne,Gulea, Mihaela
supporting information; scheme or table, p. 6553 - 6555 (2009/04/05)
Various primary 2-aminothiols have been prepared by a general and efficient method, in three steps, starting from commercially available 2-aminoalcohols and methyldithioacetate as a convenient source of sulfur.
