52264-86-5

Basic information

• Product Name: 2-(benzylsulfanyl)-1-(4-methylphenyl)ethanone
• Synonyms: 2-(benzylsulfanyl)-1-(4-methylphenyl)ethanone
• CAS NO: 52264-86-5
• Molecular Formula: C₁₆H₁₆OS
• Molecular Weight: 256.36264
• Mol File: 52264-86-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(benzylsulfanyl)-1-(4-methylphenyl)ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzylsulfanyl)-1-(4-methylphenyl)ethanone(52264-86-5)
• EPA Substance Registry System: 2-(benzylsulfanyl)-1-(4-methylphenyl)ethanone(52264-86-5)

Safety Data

• Hazardous Substances Data: 52264-86-5(Hazardous Substances Data)

Upstream product

• 100-53-8 phenylmethanethiol 
• 619-41-0 4-(bromoacetyl)toluene 
• 885517-60-2 2-acetyl-3,3-bis-allylsulfanyl-N-o-tolyl-acrylamide 
• 145508-26-5 2-(bis(methylthio)methylene)-3-oxo-N-(o-tolyl)butanamide 
• 875778-80-6 2-[bis(benzylthio)methylene]-3-oxo-N-o-tolylbutanamide 
• 850998-07-1 2-acetyl-3,3-bis-ethylsulfanyl-N-o-tolyl-acrylamide 
• 885517-59-9 2-[bis(butylthio)methylene]-3-oxo-N-o-tolylbutanamide 

Downstream Products

• 1393560-72-9 1-(benzylsulfanyl)-2-(4-methylphenyl)propan-2-ol 
• 1393560-05-8 benzyl 2-(4-methylphenyl)propyl sulfone 
• 1393559-77-7 benzyl (1E)-2-(4-methylphenyl)prop-1-en-1-yl sulfone 
• 339276-91-4 1-(benzylsulfonyl)-2-(4-methylphenyl)propan-2-ol 

Relevant articles and documents

Stevens rearrangement of thioethers with arynes: A facile access to multi-substituted β-keto thioethers

An effective method for the synthesis of multi-substituted β-keto thioethers via Stevens rearrangement of simple β-keto thioethers with arynes has been developed. In these reactions, successive C-S/C-H/C-C bonds were formed in one pot under mild and transition-metal free conditions to afford multi-substituted β-keto thioethers in moderate to good yields.

ION PAIR CATALYSIS OF TUNGSTATE AND MOLYBDATE

D The present invention relates to ion pair catalysts (I) comprising the cationic bisguanidinium ligand (A) and diperoxomolybdate anion (B). The present invention also relates to ion pair catalysts (III) comprising the cationic bisguanidinium ligand (C) and peroxotungstate anion (D). It further relates to the use of the said catalysts in the manufacture of enantiomerically enriched sulfoxides.

Enantioselective synthesis of chiral sulfones by ir-catalyzed asymmetric hydrogenation: A facile approach to the preparation of chiral allylic and homoallylic compounds

A highly efficient and enantioselective Ir-catalyzed hydrogenation of unsaturated sulfones was developed. Chiral cyclic and acyclic sulfones were produced in excellent enantioselectivities (up to 98% ee). Coupled with the Ramberg-Baecklund rearrangement, this reaction offers a novel route to chiral allylic and homoallylic compounds in excellent enantioselectivities (up to 97% ee) and high yields (up to 94%).

An efficient and odorless synthesis of thioethers using 2-[Bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as thiol equivalents

Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides 1 as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 1 commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. It is noteworthy that only a very faint odor of thiols can be perceived during both the reaction and the workup. Using 2-[bis(alkylthio)methylene]-3-oxo-N-o-tolylbutanamides as odorless thiol equivalents, an efficient and odorless synthesis of thioethers has been developed. Promoted by NaOH in EtOH, the cleavage of 2-[bis(alkylthio)methylene] -3-oxo-N-o-tolylbutanamides commences to generate thiolate anions, and the generated thiolate anions then react with halides to give various thioethers in good yield. Copyright