5228-74-0Relevant articles and documents
Enhancement of Lewis acidity by ligand-defined metal geometry: A catalytic allylation of aldehydes with allyltrimethylsilane
Kanai, Motomu,Kuramochi, Akiyoshi,Shibasaki, Masakastu
, p. 1956 - 1958 (2002)
A highly Lewis acidic aluminum complex was produced using a tridentate ligand 1. The enhanced Lewis acidity of 1-Al was attributed to the combination of a stereoelectronic effect and an electrostatic effect. Comparison with an unstrained complex 4-Al indi