52318-37-3Relevant academic research and scientific papers
A KINETIC STUDY FOR THE REACTION OF ARYLOXYTRIMETHYLSILANE WITH METHANESULFINYL CHLORIDE GIVING ARYL METHANESULFINATE
Kozuka, Seizi,Higashino, Tetsuji
, p. 2067 - 2068 (1980)
A nucleophilic attack of phenoxy-oxygen has been suggested as the mechanism of the reaction of aryloxytrimethylsilane with methanesulfinyl chloride.
The Mechanism of the Reactions of Alkoxy- and Aryloxytrimethylsilanes with Sulfinyl Chlorides. A Doubt about 4-Center Mechanism for the Bimolecula IVb-VIb Bond Cleavages
Kozuka, Seizi,Higashino, Tetsuji
, p. 1183 - 1185 (2007/10/02)
Kinetic studies have been conducted for the reactions of ethoxytrimethylsilane with benzenesulfinyl chloride and aryloxytrimethylsilane with methanesulfinyl chloride.Both the reactions were found to obey second order rate equation.A clear negative ρ value was observed for the reaction of aryloxytrimethylsilane.The solvent effects suggested that both the two reactions were quite similar in their mechanisms.Nucleophilic addition of silyl-oxygen atom to sulfinyl group has been suggested for these two reactions.
