52341-13-6

Basic information

• Product Name: dichloroplatinum(2+) (Z)-ethenediide - 2,4,6-trimethylpyridine (1:1:1)
• CAS NO: 52341-13-6
• Molecular Formula: C₁₀H₁₅Cl₂NPt
• Molecular Weight: 413.2069
• Mol File: 52341-13-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 171°C at 760 mmHg
• Flash Point: 57.2°C
• Vapor Pressure: 1.9mmHg at 25°C
• CAS DataBase Reference: dichloroplatinum(2+) (Z)-ethenediide - 2,4,6-trimethylpyridine (1:1:1)(CAS DataBase Reference)
• NIST Chemistry Reference: dichloroplatinum(2+) (Z)-ethenediide - 2,4,6-trimethylpyridine (1:1:1)(52341-13-6)
• EPA Substance Registry System: dichloroplatinum(2+) (Z)-ethenediide - 2,4,6-trimethylpyridine (1:1:1)(52341-13-6)

Safety Data

• Hazardous Substances Data: 52341-13-6(Hazardous Substances Data)

Upstream product

• 108-75-8 2,4,6-trimethyl-pyridine 
• 12012-50-9 potassium trichloro(ethene)platinate(II) 
• 123334-22-5 Zeise’s salt 
• 75094-34-7 [PtCl2(η-2-C2H4)(EtMe2CNCHCHNCMe2Et)] 
• 16405-35-9 Zeise's salt 
• 95864-86-1 Pt((CH₃)3CNC(H)C(H)NC(CH₃)3)(CH₂CH₂)Cl₂ 

Downstream Products

• 1621108-03-9 C₁₆H₂₅Cl₂NPt 
• 1258980-53-8 (+/-)-[((2,4,6-trimethylpyridine)PtCl₂)2(C₈H₁₂NTs)] 

Relevant articles and documents

Synthesis of trans -Cycloalkenes via Enantioselective Cyclopropanation and Skeletal Rearrangement

An efficient one-pot two-step procedure for asymmetric synthesis of piperidine-fused trans-cycloalkenes is reported. The method comprises the initial enantioselective installation of another cyclopropane ring onto methylenecyclopropanes and the subsequent thermal skeletal rearrangement in which the installed and inherent cyclopropane rings are both opened. A concerted mechanism is proposed for the latter thermal rearrangement reaction together with a closed transition state model.