52356-07-7Relevant academic research and scientific papers
Organoaluminum-catalyzed new alkylation of tert-alkyl fluorides: Synthetic utility of Al-F interaction
Ooi, Takashi,Uraguchi, Daisuke,Kagoshima, Naoko,Maruoka, Keiji
, p. 5679 - 5682 (1997)
tert-Alkyl fluorides have been revisited as promising alkylation agents based on the activation of fluorine as a leaving group by organoaluminums through the eminent AI-F interaction. Trialkylaluminums were found to be excellent catalysts as well as alkylation agents.
