523978-90-7

Basic information

• Product Name: Silane, [[2,5-bis(dodecyloxy)-4-iodophenyl]ethynyl]trimethyl-
• CAS NO: 523978-90-7
• Molecular Formula: C35H61IO2Si
• Molecular Weight: 668.858
• Mol File: 523978-90-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, [[2,5-bis(dodecyloxy)-4-iodophenyl]ethynyl]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [[2,5-bis(dodecyloxy)-4-iodophenyl]ethynyl]trimethyl-(523978-90-7)
• EPA Substance Registry System: Silane, [[2,5-bis(dodecyloxy)-4-iodophenyl]ethynyl]trimethyl-(523978-90-7)

Safety Data

• Hazardous Substances Data: 523978-90-7(Hazardous Substances Data)

Upstream product

• 3230-09-9 1,4-bis-dodecyloxy-benzene 
• 123-31-9 hydroquinone 
• 171368-73-3 2,5-bis(dodecyloxy)bromobenzene 
• 143-15-7 1-dodecylbromide 
• 583-69-7 2-bromobenzene-1,4-diol 
• 171368-82-4 2,5-bis(dodecyloxy)-4-bromo-1-aminobenzene 
• 171368-81-3 2,5-bis(dodecyloxy)-4-bromo-1-nitrobenzene 
• 145483-66-5 1,4-bis(dodecyloxy)-2,5-diiodobenzene 
• 1066-54-2 trimethylsilylacetylene 

Downstream Products

• 524939-97-7 4,16-bis{[2,5-didodecyloxy-4-[(trimethylsilyl)ethynyl]phenyl]ethynyl}[2.2]paracyclophane 
• 860402-25-1 4-(2,5-bis-dodecyloxy-4-trimethylsilanylethynyl-phenylethynyl)-benzoic acid 2-trimethylsilanyl-ethyl ester 
• 860402-26-2 4-[4-(2,5-bis-dodecyloxy-4-trimethylsilanylethynyl-phenylethynyl)-2,5-bis-dodecyloxy-phenylethynyl]-benzoic acid 2-trimethylsilanyl-ethyl ester 
• 1334224-74-6 1,4-bis(dodecyloxy)-2-[(trimethylsilyl)ethynyl]-5-[(2,6-di(acetylamino)pyridine-4-yl)ethynyl]benzene 
• 1334224-75-7 1,4-bis(dodecyloxy)-2-ethynyl-5-[(2,6-di(acetylamino)pyridine-4-yl)ethynyl]benzene 
• 865649-64-5 C₁₀₄H₁₇₄O₆Si₂ 
• 638212-83-6 4-[4-(2,5-bis-dodecyloxy-4-ethynyl-phenylethynyl)-2,5-bis-dodecyloxy-phenylethynyl]-benzoic acid 2-trimethylsilanyl-ethyl ester 
• 780755-58-0 4-(2,5-bis-dodecyloxy-4-ethynyl-phenylethynyl)-benzoic acid 2-trimethylsilanyl-ethyl ester 
• 870080-50-5 4-[4-{[(2'-(2'',5''-bis(dodecyloxy)-4''-(2'-trimethylsilylethynyl)phenyl)]ethynyl}-2,5-bis(dodecyloxy)phenyl)ethynyl]benzaldehyde 
• 870080-47-0 4-{[2'-(2'',5''-bis(dodecyloxy)-4''-(2'-trimethylsilylethynyl)phenyl)]ethynyl}-2,5-bis(dodecyloxy)iodobenzene 
• 870080-48-1 4-{[2'-(2'',5''-bis(dodecyloxy)-4''-(2'-trimethylsilylethynyl)phenyl)]ethynyl}benzaldehyde 
• 935529-60-5 2,5-bis(dodecyloxy)-4-(2'-trimethylsilylethynyl)triisopropylsilylacetylenylbenzene 

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A facile synthetic route to monodisperse asymmetrical oligo(phenylene- ethynylene)s

Monodisperse asymmetrical oligo(phenylene-ethynylene)s were synthesized iteratively by combining the selective deprotection and the Sonogashira coupling. Trimethylsilylethyl ester (TSE) and trimethylsilyl (TMS) were used as protecting groups for carboxyl