5240-87-9Relevant academic research and scientific papers
THERMAL REACTION OF 2,3-DIAZATETRACYCLO4,11.06,8>UNDECA-2,9-DIENES: THE NITROGEN EXTRUSION AND THE MASKED HOMODIENYL-1,5-HYDROGEN SHIFT
Ohba, Yoshihiro,Kumagai, Tsutomu,Mukai, Toshio
, p. 1361 - 1364 (2007/10/02)
Thermolyses of the title compounds produce three kinds of products which are derived from nitrogen extrusion and 1,5-hydrogen shifts.The reaction mechanism is discussed in connection with the thermal behavior of bicyclononatriene.
PHOTOREACTIONS OF 2,3-DIAZATETRACYCLOUNDECA-2,9-DIENES; THE RETRO-1,3-DIPOLAR CYCLOADDITIONS AND THE NITROGEN EXTRUSION REACTIONS
Kumagai, Tsutomu,Ohba, Yoshihiro,Mukai, Toshio
, p. 439 - 442 (2007/10/02)
The photochemical reactions of tetracyclic azo compounds (1a-b) giving 5a-b and 8a-b via diazoethane derivatives (6a-b) were investigated in addition to the nitrogen extrusion reactions leading to tetracyclononenes (4a-b).
