524960-22-3Relevant academic research and scientific papers
New stable germylenes, stannylenes, and related compounds. 1. Stable germanium(II) and tin(II) compounds M(OCH2CH2NMe2)2 (M = Ge, Sn) with intramolecular coordination metal-nitrogen bonds. Synthesis and structure
Zemlyansky, Nikolay N.,Borisova, Irina V.,Kuznetsova, Marianna G.,Khrustalev, Victor N.,Ustynyuk, Yuri A.,Nechaev, Mikhael S.,Lunin, Valery V.,Barrau, Jacques,Rima, Ghassoub
, p. 1675 - 1681 (2008/10/08)
New stable monomeric germanium(II) and tin(II) compounds M(OCH2CH2NMe2)2 (M = Ge (1); M = Sn(2)), stabilized by two intramolecular coordination M←N bonds and containing no bulky groups on the metal atoms, were synthesized. The molecular and crystal structures of these compounds, and that of the previously synthesized compound (ArO)2Sn (3; Ar = 2,4,6-(Me2NCH2)3C6H2), were determined by X-ray diffraction analysis. The electronic structures of 1 and 2 were studied by the DFT method.
