52514-35-9

Upstream product

• 39727-46-3 phenyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside 
• 52443-46-6 phenyl 2,3-anhydro-4,6-O-benzylidene-3-C-nitro-β-D-gulopyranoside 
• 39727-46-3 (4aR,6S,8aS)-8-Nitro-6-phenoxy-2-phenyl-4,4a,6,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine 
• 52443-46-6 phenyl 2,3-anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside 

Downstream Products

• 52443-51-3 methyl 4,6-O-benzylidene-2-bromo-2-deoxy-β-D-ribo-hexopyranoside-3-ulose 
• 52443-51-3 methyl 4,6-O-benzylidene-2-bromo-2-deoxy-α-D-ribo-hexopyranoside-3-ulose 
• 52443-51-3 methyl 4,6-O-benzylidene-2-bromo-2-deoxy-α-D-xylo-hexopyranosid-3-ulose 

Relevant academic research and scientific papers

PREPARATION OF METHYL 4,6-O-BENZYLIDENE-2-CHLORO- AND -2-BROMO-α- AND β-D-xylo-HEXOPYRANOSID-3-ULOSES AND THEIR α-D-ribo ISOMERS, AND FORMATION OF GLYCOSID-3-ULOSE HYDRATES FOR THE β-D-xylo ISOMERS

The title glycosid-3-uloses were prepared from 3-nitro-β-D-threo-hex-2-eno-pyranoside derivatives. 1H-N.m.r. spectral studies revealed that the 2-bromo- and 2-chloro-β-D-xylo-hexopyranosid-3-uloses readily equilibrated with their hydrates, but the remaini

DENITRATION OF CARBOHYDRATE α-NITROEPOXIDES BY NUCLEOPHILES

Several nucleophiles were separately treated with methyl and phenyl 2,3-anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside, to give 2-substituted aldos-3-ulose derivatives.In the latter case, the subsequent β-elimination of the aglyconic phenyl