52524-95-5Relevant academic research and scientific papers
An Approach to Carbide-Centered Cluster Complexes
Reinholdt, Anders,Majer, Sean H.,Gelardi, Rikke M.,Macmillan, Samantha N.,Hill, Anthony F.,Wendt, Ola F.,Lancaster, Kyle M.,Bendix, Jesper
supporting information, p. 4812 - 4819 (2019/04/25)
We report the first examples of the carbide ligand in (Cy3P)2Cl2Ru≡C (RuC) developing into a μ3 ligand toward metal centers. Conventionally, sterics exclude this coordination mode, but Fe2(CO)9 and Co2(CO)8 expel bridging CO ligands upon reaction with RuC to form trimetallic (Cy3P)2Cl2Ru=CFe2(CO)8 (RuCFe2) and (Cy3P)2Cl2Ru=CCo2(CO)7 (RuCCo2) complexes. Thus, the proximity offered by metal-metal associations in bimetallic carbonyl complexes allows the formation of trinuclear carbide complexes as verified by NMR, M?ssbauer, and X-ray spectroscopic techniques.
Isocyanide-promoted ylidene transfer to phosphorus: Rearrangement in the first-generation grubbs complex
Galan, Brandon R.,Pitak, Mateusz,Keister, Jerome B.,Diver, Steven T.
, p. 3630 - 3632 (2009/02/05)
Carbon monoxide or an aryl isocyanide promotes a benzylidene carbene transfer from ruthenium to tricyclohexy-lphosphine in the first-generation Grubbs carbene complex. The resulting ruthenium(II) complexes have been isolated and structurally characterized by X-ray crystal structure analysis; aprobable mechanism for the ligand-promoted transformation is also discussed.
