52579-45-0Relevant academic research and scientific papers
New applications of hetaryl thioketones for the synthesis of hetaryl-substituted ethenes via 'two-fold extrusion reaction'
Mlostoń, Grzegorz,Urbaniak, Katarzyna,Pawlak, Aneta,Heimgartner, Heinz
, p. 127 - 139 (2016)
A series of aryl/hetaryl thioketones was applied for the reactions with aryl/hetaryldiazomethanes yielding, after elimination of N2, the corresponding thiiranes. The relatively unstable dihetaryldiazomethanes were generated in situ from the corresponding hydrazones by oxidation with DMSO. The obtained thiiranes were converted into tetraaryl/hetaryl-substituted ethenes in good yields by desulfurization performed with tris(diethylamino)phosphine ((Et2N)3P).
